Thirty Six Years of Research on the Selective Reduction and Hydroboration

Jin-Soon Cha
2011 Bulletin of the Korean Chemical Society (Print)  
thirty six years, the author and his collaborators have developed a variety of reducing and hydroborating agents, and applied them to organic synthesis, which involves the 1,2-reduction of α,βunsaturated carbonyl compounds, stereoselective reduction of cycloalkanones, regioselective ring-opening of epoxides, partial reduction of carboxylic acid derivatives to aldehydes, regioselective addition to carbon-carbon multiple bonds, etc. by utilizing metal hydrides and the newly-devised the
more » ... nndorf-Verley (MPV) type reagents. Such developments provide a new synthetic methodology making possible valuable selective reductions and hydroborations, not practical previously.
doi:10.5012/bkcs.2011.32.6.1808 fatcat:n743yc7gn5eaxapdohbyhbqtie