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A microcalorimetric study of the influence of lead ions on the heat of dilution of potassium halides, and the derived thermodynamics of ion association in solutions of the lead halides
[article]
2012
Recently the association constants for the formation of the complex ions PbCl+, PbBr+, PbI+ have been determined by measurements of the ultraviolet absorption spectra of the corresponding lead halide solutions. In determining these association constants no assumptions are made about the nature of the complex ion except that a chemical potential may be assigned to it and that the law of Mass Action is applicable to the equilibrium Fb++ + X- [] PbX+ where X- = Cl=, Br-, or I-. According to the
doi:10.26021/8179
fatcat:aexaumo2ynfpxdyp7ye6gdvwkq