Synthesis and thermodynamics of the reactions of [Pd(Eten)(H2O)2]2+ with ligands of biological significane with reference to the antitumour activity

Fawzia Al-Kallaf, Perihan A. Khalf-Allaa, Abeer Al-Bassam, Mohamed M. Shoukry
2016 JOURNAL OF ADVANCES IN CHEMISTRY  
Pd(Eten)Cl2 complex, where Eten = N-ethylethylenediamine , was synthesized and characterized by elemental analysis and spectroscopic techniques. The stoichiometry and stability of the complexes formed between [Pd(Eten)(H2O)2]2+ and various biologically relevant ligands as adenine, adenosine, adenosine-5'-monophosphate and some selected peptides were investigated at 25ºC and 0.1 M ionic strength. The speciation diagrams of the complexes formed in solutions are evaluated. Thermodynamic parameters
more » ... for Pd(Eten)-glycylglycine complexes were estimated.
doi:10.24297/jac.v11i1.2222 fatcat:t6ajlqkf3nc2ti3oyx555l3ssu