The crystal and molecular structures of N,N'-o-phenylenebis(salicylaldiminato)palladium(II) and μ-N,N'-o-phenylenebis(salicylaldiminato){bis[(2-C,N-acetophenone oxime)palladium(II)]}

G. D. Fallon, B. M. Gatehouse
1976 Acta Crystallographica Section B  
Pd(salophen) crystals are orthorhombic, space group P21212~, with a=16.786 (16), b=17.677 (18), c= 5.336 (6) A, Z= 4. The structure was solved by Patterson and Fourier techniques, refined to R= 0.078 from 995 observed reflexions, and consists of discrete molecules, the Pd atom having approximate square-planar geometry. (ApoPd)2salophen crystals are monoclinic, space group P21/c, with a=7.109 (4), b=25"321 (13), c= 17.979 (8)/1" fl= 107.8 (4) °, Z=4. The structure was solved by Patterson and
more » ... y Patterson and Fourier techniques, refined to R = 0.061 from diffractometer data (3119 observed reflexions), and consists of discrete binuclear units, the salophen ligand bridging the two metal centres. The squareplanar coordination about each Pd atom is completed by the acetophenone oxime ligand.
doi:10.1107/s0567740876008327 fatcat:pxthfvcrlrgglp6vl2qs4bdrzm