Synthesis and Studies of -bis ( Thiolethylsuphide-1, 3, 4- Oxadiazole-2yl) Ethane and it's Complexes with (M (II): Cu, Ni, Co, Hg)

Ali I. Abdullah, Falih H. Musa, Hikmat A. Mohammad
2009 Rafidain journal of science  
The new ligand 2 , 1 -bis ( 2 5 − -thiolethysulphide) -1, 3, 4-oxadiazole-2yl) ethane (BTESOE) was prepared from the reaction of 1 -, 2 --bis-( 2 5 − -chloro ethylsulphide)-1,3,4-oxadiazol-2yl) ethane with sodium sulphide in aqueous ethanol solution. The ligand was characterized using IR, UV/Vis, 1 H-n.m.r, 13 C-n.m.r, mass spectroscopies and molar conductivity. BTESOE was employed to synthesize four complexes with metals (M (II): Cu, Ni, Co and Hg), the complexes were studied using IR, UV/Vis,
more » ... atomic spectroscopies, molar conductivity and magnetic susceptibilities techniques. The results showed that each of these complexes has an octahedral geometry structures.
doi:10.33899/rjs.2009.41330 fatcat:ba6qxxpl6zb4zpy4ym2smjj23q