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Vibrational and structural properties of tetramethyltin under pressure
Journal of Chemical Physics
The vibrational and structural properties of a hydrogen-rich group IVa hydride, Sn(CH 3 ) 4 , have been investigated by combining Raman spectroscopy and synchrotron x-ray diffraction measurements at room temperature and at pressures up to 49.9 GPa. Both techniques allow the obtaining of complementary information on the high-pressure behaviors and yield consistent phase transitions at 0.9 GPa for the liquid to solid and 2.8, 10.4, 20.4, and 32.6 GPa for the solid to solid. The foregoing soliddoi:10.1063/1.4774022 pmid:23320683 fatcat:v74jvi6u2nhzvcb7d7rwvjdz5u