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Two mononuclear Schiff base manganese(III) complexes, [MnL(N 3 )(OH 2 )]·CH 3 OH (1) and [MnL(NCS)(OH 2 )] · H 2 O (2), where L is the dianionic form of N,N'-bis(5-nitrosalicylidene)ethane-1,2-diamine, have been prepared and characterized by elemental analysis, IR and UV-Vis spectroscopy and single crystal X-ray diffraction. The Mn atom in each complex is in an octahedral coordination. Molecules of the complexes are linked through intermolecular hydrogen bonds. Catalytic properties fordoi:10.17344/acsi.2017.3416 fatcat:rtf7ibulgrfyjcsqpdtqtfjqb4