Synthesis and styrene copolymerization of novel trisubstituted ethylenes: 9. Halogen, methyl, methoxy and nitro ring-substituted octyl phenylcyanoacrylates [post]

Christian D. Etnyre, Carlos S. Font, Azxiel Frutos, Emily L. Fung, Ashley G. Gil Cardenas, Cassandra E. Gomez, Leticia Martinez, Alexander P. Lopez, William S. Schjerven, Gregory B. Kharas, Ruanum H. Razak, Sara M. Rocus (+1 others)
2021 unpublished
Novel trisubstituted ethylenes, halogen, methyl, methoxy and nitro ring-substituted octyl phenylcyanoacrylates, RPhCH=C(CN)CO2CH2(CH2)6CH3 (where R is 2-chloro-6-fluoro, 3chloro-4-fluoro, 2-chloro-5-nitro, 4-chloro-3-nitro, 5-chloro-2-nitro, 5-iodo-2-methoxy, 2,4,5-trimethyl, 2,4,6-trimethyl, pentamethyl, 2,3-dimethyl-4-methoxy, 2,5-dimethyl-4methoxy, 2,4-dimethoxy-3-methyl) were prepared and copolymerized with styrene. The ethylenes were synthesized by the piperidine catalyzed Knoevenagel
more » ... nsation of ringsubstituted benzaldehydes and octyl cyanoacetate, and characterized by CHN analysis, IR, 1 H and 13 C NMR. All the ethylenes were copolymerized with styrene in solution with
doi:10.33774/chemrxiv-2021-k812v-v20 fatcat:33uwzod7wzdszhiyjmmdfqgrum