Darstellung und Eigenschaften von Natrium-und Kaliumtetrakis(trimethylsilyl)aluminat-Komplexen / Preparation and Properties of Sodium and Potassium Tetrakis(trimethylsilyl)aluminate Complexes

Lutz Rösch, Gerald Altnau
1980 Zeitschrift für Naturforschung. B, A journal of chemical sciences  
Sodium and potassium tetrakis(trimethylsilyl)aluminate are synthesized by reaction of sodium or potassium with bis(trimethylsilyl)mercury and tris(trimethylsilyl)aluminium. Sodium and potassium tetrakis(trimethylsilyl)aluminate complexes, coordinated with diethylether, tetrahydrofurane or 1,2-dimethoxyethane are available by dissolving the unsolvated compounds in the ethers. The IR, Raman, 1H and 13C NMR spectra are discussed.
doi:10.1515/znb-1980-0213 fatcat:iwrtp26c3jfh7k7yrzozcfln3e