Double α,α CH Bond Insertion into sp3 CH2 Moiety: Synthesis of a Fe Carbene bis-Hydride Dinitrogen Complex

Julien Petit, Anthony Cavaillé, Nathalie Saffon, Marie Fustier-Boutignon, Nicolas Mézailles
2021 Dalton Transactions  
Reduction of high spin paramagnetic complex [(κ2-P, P'-PCH2PCy)FeCl2] 2 by two electrons under N2 resulted in the formation of two isomeric low spin diamagnetic complexes 3trans and 3cis [Fe(κ3-P,C,P'-PCPCy)(H)2(N2)]. Cristallization...
doi:10.1039/d1dt00610j pmid:34159989 fatcat:m4w3oor6pnbqlfedr7pgafkjca