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Temperature-programmed desorption (TPD) results after chemisorption of carbon monoxide (CO) and carbon dioxide (CO,) on polycrystalline graphite are presented. CO adsorbs onto graphite with a very low sticking coefficient. After CO Chemisorption, CO (mass 28 amu) desorbs in two temperature regions, between 400 and 700 K and between 1000 and 1300 K, and COz (mass 44 amu) desorbs below 950 K. The intensity of the COz signal is less than 1 order of magnitude lower than the CO intensity. After C02doi:10.1021/j100331a039 fatcat:ts7qf73evfbynef6lwvosccxay