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Correlation between Yield and Reduced Mass of Raw Materials in Intermolecular and Intramolecular Cyclization Reactions
[post]
2020
unpublished
Preserved Fulltext
Correlation between yield and reduced mass of raw materials in intramolecular C-N, C-C, C-O coupling reactions and intramolecular/intermolecular Diels-Alder reactions was revealed. The regression equation was found to be the same as that of intermolecular reactions; yield = -0.1861<i>M</i><sub>AB</sub>/(<i>n</i><sub>A</sub><i>n</i><sub>B</sub><i>n</i><sub>I</sub>)+100.0, where <i>M</i><sub>AB</sub> is the reduced mass per mole and <i>n</i><sub>A</sub> and <i>n</i><sub>B</sub> are the total
doi:10.26434/chemrxiv.13350974
fatcat:gsw2nbwwkbg4dge3who6mxyjii