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Nano-TiO 2 and its modification with gallium (nano-TiO 2 -Ga) and zirconium (nano-TiO 2 -Zr) were used here as nanofillers in production of linear low-density polyethylene (LLDPE). The nanoparticles were immobilized by modified-methyl aluminoxane (MMAO) to be a catalytic filler prior to introducing into the in situ polymerization of ethylene and 1-hexene using zirconocene catalyst, and consequently produced LLDPE/TiO 2 nanocomposites. It was found that the modified nano-TiO 2 by Ga and Zr candoi:10.4186/ej.2013.17.3.33 fatcat:ijkhnb6mcffl7ioxz667m5aka4