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Synthesis, Electrochemical Characterization, and Water Oxidation Chemistry of Ru Complexes Containing the 2,6-Pyridinedicarboxylato Ligand
[component]
unpublished
The tridentate meridional ligand pyridyl-2,6-dicarboxylato (pdc 2-) has been used to prepare complexes Ru II (pdc-ҡ 3 -N 1 O 2 )(DMSO)2Cl] (1 II ), Ru II (pdc-ҡ 3 -N 1 O 2 )(bpy)(DMSO)] (2 II ) and {[Ru III (pdc-ҡ 3 -N 1 O 2 )(bpy)]2(-O)} (5 III,III ) where bpy: 2,2'-bipyridine. All complexes have been fully characterized through spectroscopic, electrochemical and single crystal X-ray diffraction techniques. Compounds 1 II and 2 II show SO linkage isomerization of the DMSO ligand upon
doi:10.1021/acs.inorgchem.0c01215.s001
fatcat:2pnupdza35b4dcztahogmu3qz4