Ag/ZnO/PMMA nanocomposites for an efficient water reuse

Alessandro Di Mauro, Clayton Farrugia, Stephen Abela, Paul Refalo, Maurice Grech, Luciano Falqui, Giuseppe Nicotra, Gianfranco Sfuncia, Antonio Mio, Maria Antonietta Buccheri, Giancarlo Rappazzo, Maria Violetta Brundo (+5 others)
2020 ACS Applied Bio Materials  
This work attempts to produce photocatalytic surfaces for large-scale applications by depositing nanostructured coatings on polymeric substrates. ZnO/poly(methyl methacrylate) (PMMA) composites were prepared by low-temperature atomic layer deposition (ALD) of ZnO on PMMA substrates. In addition, to increase the photocatalytic and antibacterial activities of ZnO films, Ag nanoparticles were added on ZnO surfaces using plasma-enhanced ALD. The morphology, crystallinity, and chemical composition
more » ... the specimens were meticulously examined by scanning and transmission electron microscopies, energy-dispersive X-ray spectroscopy, and X-ray diffraction analyses. The noteworthy photocatalytic activity of the nanocomposites was proved by the degradation of the following organic pollutants in aqueous solution: methylene blue, paracetamol, and sodium lauryl sulfate. The antibacterial properties of the samples were tested using Escherichia coli as a model organism. Moreover, the possible toxic effects of the specimens were checked by biological tests. The present results unambiguously indicate the Ag/ZnO/PMMA nanocomposite as a powerful tool for an advanced wastewater treatment technology.
doi:10.1021/acsabm.0c00409 pmid:35025440 fatcat:emcfejsrpfacxnvw4v6sx3gruq