The synthesis of SSZ-13 with mixed template and it's catalytic performance for methanol to olefins reaction

Yunshui Deng, Yuan Li, Yu Su
2012 Proceedings of the 2nd International Conference on Electronic and Mechanical Engineering and Information Technology (2012)   unpublished
In order to reduce the cost, a mixed template of BTMA + and TMADA + was used to synthesize SSZ-13 zeolite. The effects of the compositions of the mixed template on structure and morphology were characterized by XRD, SEM. The catalytic performance of prepared SSZ-13 was investigated in a fixed-bed reactor at 450 o C for the methanol-to-olefin reaction ,the weight hourly space velocity (WHSV) was 1.75 h -1 . The results show that cubic SSZ-13 crystals with good crystallinity and small size
more » ... ution (the average particle size of 0.3 um) was synthesized with the n(TMADA +) /n(TMADA + +BTMA + ) is 0.3. In the methanol-to-olefin reaction, The yield of olefin can reaches 88%, and the lifetime of the catalyst is above 200min.
doi:10.2991/emeit.2012.216 fatcat:ftihhufhjvbk3f3e5btkyktvya