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The tube axis and entanglements in polymer melts
2014
Soft Matter
Although the tube theory is very popular and successful, the tube concept remains evasive and ill defined. This paper proposes a simple computer algorithm to construct the tube axis as a center line of the cloud of chain configurations at different moments of time. We test this algorithm on trajectories generated from simulations of concatenated well entangled ring polymers, thus avoiding all disentanglement processes. We find that entanglements are clearly manifested through the curvature of
doi:10.1039/c3sm52575a
pmid:24651963
fatcat:ipb6pupjkfdvtf5rw65m2w4lvq