Phase Diagramof CsF-RbF System

DING Yi-Min, 上海大学理学院化学系, 上海 200444, Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, P. R. China, ZHANG Ting-Ting, LIU Xu, CHEN Nian-Yi
2007 Wuli huaxue xuebao  
Thedatafrom75knownphasediagramsofMX鄄M忆X(X=F,Cl,Br,I;MandM忆aremonovalentmetals) systemswereprocessedbyusingthesupportvectormachine鄄atomicparameterpatternrecognitionmethod.The regularityoftheformationofsolidsolutioninthesesystemswasfound.Themathematicalmodelobtainedpredicted thattheCsF鄄RbFsystemshouldformsolidsolution.ThephasediagramoftheCsF鄄RbFsystemwasdeterminedusing differentialthermalanalysis.Theresultsindicatedthattherewasnotemperatureminimumeitherinthesolidusorinthe
more » ... dusandconfirmedthatthephasediagramwasbelongedtothecontinuoussolidsolubilitysystem,whichwasin agreementwiththecomputerizedresultsofthermodynamicsinthereference.
doi:10.3866/pku.whxb20070432 fatcat:gju62vg45vdgvca5xj5rwyuljq