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Stratospheric photodissociation of several saturated perhalo chlorofluorocarbon compounds in current technological use (fluorocarbons-13, -113, 114, and -115)
The Journal of Physical Chemistry
Photon absorption cross sections have been measured in the stratospherically important 1849-2273-A range for CClF3 (fluorocarbon-13), CC12FCClFz (FC-113), CClFzCClF2 (FC-1141, and CClFzCF3 (FC-115). Atmospheric residence times have been calculated for these four compounds, and for CC13F (FC-11) and CC12Fz (FC-121, with the assumption that the molecules are removed only by direct solar photolysis or by reaction with O('D) atoms. Four different eddy diffusion models were used for stratosphericdoi:10.1021/j100490a001 fatcat:hf3dzjg36jaqhgo2qh3nhtn5gi