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Chemistry Department, Luoknow University, Lucknow-226 007 Manuscript received 6 January 1986, revised 21 August 1986, accepted 17 February 1987 Several new bi.(dithiocarbamato)oxovanadium(II) of the formula, VO(dtc), have been prepared and characterised on the basis of analytical and spectral data Their interaction with soft acceptors has yielded molecular adducts of the formula, VO(dtc)2 2M'X2 or VO(dtc)2,2MX, where M'=Hg or Cd; M'=Ag, X=CI, SCN, OCOCF2 and OClO2doi:10.5281/zenodo.6218494 fatcat:nuuue2sfzrhjtpr4ifpac2nwzi