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Critique of the foundations of time-dependent density-functional theory
2007
Physical Review A. Atomic, Molecular, and Optical Physics
The general expectation that, in principle, time-dependent density functional theory (TDDFT) be an exact formulation of the time-evolution of an interacting N-electron system is critically reexamined. It is demonstrated that the previous TDDFT foundation, resting on three theorems by Runge and Gross (RG) [Phys.Rev.Lett.52, 997(1984)], is invalid because undefined phase factors corrupt the RG action integral functionals. Our finding confirms much of a previous analysis by van Leeuwen [Int. J.
doi:10.1103/physreva.75.022513
fatcat:sumuxac565glbb7m5nyyq3oriu