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Studies of radiolytically generated radical cations in aromatic hydrocarbon solvents have led to the first direct characterizationof monomericthioether radical cations in liquid solution. Observation of these very reactive chemical intermediates is made possible by the great sensitivity of fluorescence-detected magnetic resonance (FDMR) and by solvent stabilization of the thioether radical cations via electron donation. Monomeric thioether radical cationsin arene solvents such as toluene existdoi:10.2172/10132711 fatcat:izyugsdlvvbtvfsqzytz2m4jkq