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The phenomenology and defects in former models are presented. A model for obtaining the current-potential and current-frequency relation is set up. The interaction energy of a photoelectron with a molecule adsorbed on the electrode is obtained by considering the Coulomb interaction between the electron and the -l-ve and -ve centres of the water dipole. Coulomb and Born interactions are accounted for. The barrier height is evaluated in terms of these potential energies. The equation for thedoi:10.1007/978-1-4684-2493-5_12 fatcat:urmp2fb3fnan7dgpinkzhlnzhq