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On the formation of gold nanoparticles from [AuIIICl4]− and a non-classical reduced polyoxomolybdate as an electron source: a quantum mechanical modelling and experimental study
2016
New Journal of Chemistry
DFT calculations and experimental data prove that the [Na{(MoV2O4)3(μ2-O)3(μ2-SO3)3(μ6-SO3)}2]15− POM is capable of completely reducing Au(iii) to Au(0).
doi:10.1039/c5nj02773j
fatcat:tjvkld72rrffbdvpe2djcd47wy