A Novel Iron(III) Selective Membrane Electrode Containing a Tripodal Polycatacholamine as Sensor

Rati Kanta Bera, Suban K Sahoo, Minati Baral, B.K. Kanungo
2011 Bulletin of the Korean Chemical Society (Print)  
A novel poly(vinylchloride)-based membrane sensor using N 1 ,N 3 ,N 5 -tris(2-(2,3-dihydroxybenzylamino)ethyl)cyclohexane-1,3,5-tricarboxamide (CYCOENCAT, L) as ionophore has been prepared and explored as Fe 3+ selective electrode. The membrane electrode composed of ionophore, poly(vinylchloride) and o-nitropheyloctyl ether in the optimum ratio 4:33:63 gave excellent potentiometric response characteristics, and displayed a linear log[Fe 3+ ] versus EMF response over a wide concentration range
more » ... 1.0 × 10 −5 -1.0 × 10 −1 M with super nernstian slope of 28.0 mV/decade and the detection limit of 8.0 × 10 −6 M. The proposed ion selective electrode showed fast response time (< 15 s), wide pH range (3.0-7.0), high non-aqueous tolerance (up to 20%) and adequate long life time (120 days). It also exhibited very good selectivity for Fe 3+ relative to a wide variety of alkali, alkaline earth, transition and heavy metal ions. Further, the analytical applicability of the sensor was tested as an indicator electrode in the potentiometric titration of Fe 3+ with EDTA.
doi:10.5012/bkcs.2011.32.10.3592 fatcat:k3zbikw2cneydbpmmggecvumt4