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Crystal structure of bis(thiocyanato)(γ-C-meso-5,5,7,12,12,14-hexamethyl- 1,4,8,11-tetraazacyclotetradecanecopper(II), C18H36CuN6S2

H.-L. Zhu, Q.-X. Liu, X. Liu
2003 Zeitschrift für Kristallographie - New Crystal Structures  

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C 18H36CuN6S2, monoclinic, P121/c1 (No. 14), a = 7.691(1) Å, b = 9.449(3) Å, c = 16.380(2) Å, b = 101.08(2)°, V = 1168.1 Å 3 , Z = 2, R gt(F) = 0.037, wRref(F 2 ) = 0.098, T = 293 K. Source of material The ligand (called " tet a") was prepared according to the method of Curtis [1] . For the preparation of [Cu(tet a)(NCS) 2], stoichiometric amounts of copper(II) perchlorate, sodium thiocyanate (two equivalent) and tet a were mixed in water and stirred for 1h during which time tet a dissolved in
more » ... ater and the solution was slowly evaporated to give red prismatic crystals. Analysis, calculated for C 18H36N6S2Cu:
doi:10.1524/ncrs.2003.218.2.259 fatcat:3rwbetjapra4zidzy3idg67jby
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H.-L. Zhu, Q.-X. Liu, X. Liu. "Crystal structure of bis(thiocyanato)(γ-C-meso-5,5,7,12,12,14-hexamethyl- 1,4,8,11-tetraazacyclotetradecanecopper(II), C18H36CuN6S2." Zeitschrift für Kristallographie - New Crystal Structures 218.2 (2003)