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A Small Organic molecule Based on Benzothiadiazole for Electrocatalytic Hydrogen Production
[post]
2021
unpublished
Preserved Fulltext
A small organic molecule 2,1,3-benzothiadiazole-4, 7-dicarbonitrile (BTDN) is assessed for electrocatalytic hydrogen, showing a hydrogen production faradaic efficiency of 82% in presence of salicylic acid. The key catalytic intermediates of reduced species BTDN−• and protonated intermediates are identified and characterized by using various spectroscopic methods and density functional theory (DFT) based calculations. With the experimental and theoretical results, a catalytic mechanism of BTDN for electrocatalytic H2 evolution is proposed.
doi:10.33774/chemrxiv-2021-kwrtm-v2
fatcat:jvnxniz6tbhlhlvjv3jdjdid2y