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Synthesis and Characterization of Pd(II) And Pt(II) Complexes with Bis [Hg (2-Apt)] Compound
2018
Kirkuk University Journal-Scientific Studies
The reaction of one mole of Hg(II) acetate with two mole of 2-amino thiophenol gave one mole of [Hg(2-apt)] compound. While the reaction of one mole of [Hg(2-apt)] with two moles of MCL2 salt. Produced new complexes in general formula [M2{Hg(2-apt)Cl4] where M=Pt(II) or Pd(II).All the prepared complexes were identified using FT-IR, 1H-NMR,13C-NMR,elemental analyses (CHNS) and molar conductivity. The results exhibited that metal bounded to the ligand via S and N in squar planer geometries. 21
doi:10.32894/kujss.2018.13.3.2
fatcat:ucdnroqh25anfg3ukoyb5fpmmi