Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives

V. C. Gonçalves, C. A. Olivati, A. J. F. Carvalho, D. T. Balogh
2013 Journal of Nanomaterials  
The resistance to photodegradation of poly[(2-methoxy-5-n-hexyloxy)-p-phenylene vinylene] (OC1OC6-PPV) films was significantly enhanced by the use of poly(vinyl alcohol) 99% hydrolyzed as protective coating. The deposition of poly(vinyl alcohol) onto OC1OC6-PPV films did not affect the absorption and the emission spectra of the luminescent polymer. The protected film showed 5% drop on the absorbance at 500 nm after 270 hours of light exposure while the unprotected film completely degraded in
more » ... same conditions. The conductivity of the protected film remained stable (around7×10−10 S/m) while the value for the unprotected one dropped around two orders of magnitude after 100 hours of light exposure.
doi:10.1155/2013/160464 fatcat:bncosvmt7vdwrfpcfrywpwlsiq