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The μ-nitrido complexes [Mo2NC19]2⊖ and [Mo2NCl9]⊖, with PPh3Me⊕ as the counter ions, are prepared by reactions of [MoNC14]2⊖ and [MoNCl4]⊖, respectively, with molybdenum pentachloride in CH2Cl2. With POCl3 [Mo2NC19]2⊖ forms the donor-acceptor complex [Mo2NCl9(POCl3)]2⊖, whereas with acetonitrile disproportionation occurs, [MONCI4]⊖ and [MoCl5(CH3CN)]⊖ being formed, respectively. The IR spectra are discussed.doi:10.1515/znb-1986-0623 fatcat:z5krtbjgtra4vod3kn4dgdbiru