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Proximity Effect in Crystalline Framework Materials: Stacking-Induced Functionality in MOFs and COFs
[post]
2019
unpublished
<div>Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) consist of molecular building blocks being stitched together by strong bonds. They are well known for their porosity, large surface area, and related properties. The electronic properties of most MOFs and COFs are the superposition of those of their constituting building blocks. If crystalline, however, solid-state phenomena can be observed, such as electrical conductivity, substantial dispersion of electronic bands,
doi:10.26434/chemrxiv.9912812.v1
fatcat:wgmvzg7hfrdwfilxjowwucuwdu