Bis(μ-4-phenylpyridineN-oxide-κ2O:O)bis[bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II)]

Ana I. Ramos, José A. Fernandes, Patrícia Silva, Paulo J. A. Ribeiro-Claro, Susana S. Braga, Filipe A. Almeida Paz
2010 Acta Crystallographica Section E  
Key indicators: single-crystal X-ray study; T = 150 K; mean (C-C) = 0.004 Å; disorder in main residue; R factor = 0.048; wR factor = 0.139; data-to-parameter ratio = 16.2. The asymmetric unit of the title compound, [Cu 2 (C 5 HF 6 O 2 ) 4 -(C 11 H 9 NO) 2 ], contains one half of the centrosymmetric dinuclear complex. The coordination geometry of the Cu II atom is octahedral, exhibiting a typical Jahn-Teller distortion. One trifluoromethyl group is rotationally disordered between two
more » ... in a 1:1 ratio. Acta Cryst. (2010). E66, m824-m825 Ramos et al. [Cu 2 (C 5 HF 6 O 2 ) 4 (C 11 H 9 NO) 2 ] m825 supporting information sup-1 Acta Cryst. (2010). E66, m824-m825 supporting information Acta Cryst. (2010). E66, m824-m825 [
doi:10.1107/s1600536810022567 pmid:21587739 pmcid:PMC3006976 fatcat:6vfbsvunojawlnw6xx632gpmo4