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The Enantiomers of Trinorbornane and Derivatives Thereof
2020
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Herein, we report the synthesis of the enantiomers of trinorbornane, a tetracyclic saturated hydrocarbon with the chemical formula C11H16. The preparation of these rigid carbon scaffolds was enabled by the successful chiral separation of its tricyclic precursor, thus allowing the enantiomers to be synthesized through a reductive radical cyclization reaction. Assignment of the absolute conformation of the enantiomers was achieved through VCD experiments. Further, we report an alternative
doi:10.5445/ir/1000118685
fatcat:u6yskwrflzb3je43acfif5sar4