A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2020; you can also visit the original URL.
The file type is
Diamagnetic clusters [Mo3X-μ-(S2)3-μ3(S)(R2PS2)3] 2-4 (2: X = Cl; 3: X = Br; 4: X = I; 2-4: a: R = Et; b: R = Pr; c: R = Bu) are conveniently obtained by reaction of [Mo3S7(R2PS2)3]+(R2PS2)- 1 either with alkyl halides RX or with tetraalkylammonium halides R4NX. Between halogen X and one of the S atoms of each disulfido bridge there exist bonds which seem to be mainly of covalent character. Thus X is incorporated into the cluster core leading to a cubane type structure. [Mo3ClS7(Et2PS2)3] formsdoi:10.1515/znb-1991-1112 fatcat:66x4l42f3vfcpa47o27godhk5u