In this paper, the compressive strength and electrochemical impedance spectroscopy (EIS) of red mudcoal metakaolin (RM-CMK) geopolymers with different Na/Al atomic molar ratios at the age of 28 d were tested and analyzed. The Na/Al atomic molar ratio had significant influence on the compressive strength and EIS of the RM-CMK geopolymers. With increasing Na/Al, the compressive strength of the RM-CMK geopolymer first increased and then decreased. When Na/Al was 1.0, the compressive strength

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... d the maximum. The EIS results yielded a Nyquist diagram that presented flat capacitive reactance arcs in the high-frequency region and insignificant diffusion curves in the low-frequency region. The Bode diagram showed that with increasing Na/Al, the peak values of the impedance modulus and phase angle both first increased and then decreased. When Na/Al was 1.0, the peak values of the impedance modulus and phase angle reached the maximum. Combined with the variation law of EIS, the equivalent circuit of the RM-CMK geopolymer was determined to be Re(C(RctW)). In addition, by means of a scanning electron microscope (SEM), images of the RM-CMK geopolymer microstructure were obtained. The changes in the strength and electrochemical responses of the RM-CMK geopolymer were explained from the microscopic perspective. In this study, EIS was used to test and analyze the electrochemical impedance characteristics of the geopolymer. This proved the feasibility of the application of EIS technology to geopolymer strength analysis. It also provided new ideas and means for the nondestructive testing technology of geopolymers.