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Asymmetric total synthesis of eicosanoid
2005
ARKIVOC
Preserved Fulltext
An asymmetric total synthesis of eicosanoid 4 starting from 2,2-dimethyl-(R)-1,3-dioxolane-4carbaldehyde is described. The key steps involved for the synthesis include modified Simmons-Smith cyclopropanation, stereoselective reduction, ring-closing metathesis (RCM) and Nozaki-Hiyama-Kishi coupling reaction.
doi:10.3998/ark.5550190.0006.316
fatcat:kg3palxqnfa7nonzbglc2wzcmy