Thermal Decomposition Of Poly (vinyl Chloride): Kinetics Of Generation And Decay Of Hydrogen Chloride In Large And Small Systems And The Effect Of Humidity

C. Bertelo, W. Carroll, M. Hirschler
1986 IAFSS - The International Association for Fire Safety Science : proceedings  
Experiments in which PVC wire insulation was decomposed by an electrical overload in a plenum or in a 200~PMMA box showed that the highest concentration of HCl in the atmosphere was always less than 40% of the theoretical amount of chlorine in the original sample. Furthermore. this concentration quickly decays to a level that is dependent on humidity, but never more than 4% of the theoretical maximum. A mathematical model was used to determine a number of parameters that describe the system.
more » ... same model applies to both large and small scale tests. This treatment showed that less than 48% of the chlorine in the wire reached the atmosphere. It also showed that the rate of decay was primarily dependent on the rate of transport in the system, producing a half life of 5-6 min without external agitation. Furthermore, the final HCI concentration was found to be dependent on relative humidity, and on surface composition (painted gypsum or PMMA).
doi:10.3801/iafss.fss.1-1079 fatcat:wqbakv3amzee7ci7txcjkb2xdq