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Simulation of methane oxidation on Pt
2007
Journal of Chemical Physics
The authors present a generic model of CH 4 oxidation on Pt with the emphasis on the role of surface-oxide formation. The latter process is treated in terms of the theory of first-order phase transitions. The corresponding Monte Carlo simulations indicate that the surface-oxide formation may result in stepwise features in the reaction kinetics. Specifically, with increasing CH 4 pressure and/or decreasing O 2 pressure, the model predicts a sharp transition from a low-reactive state with the
doi:10.1063/1.2743403
pmid:17600433
fatcat:2y7cnujabvdzvga5bo4qeajb3m