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Kinetic Aspects of Tetrahydrobenzo[b]pyran Formation in the Presence of Agar as a Green Catalyst: A Mechanistic Investigation
2016
Biosciences Biotechnology Research Asia
The kinetic and mechanism of the reaction between benzaldehyde, malononitrile and dimedone has been studied in the presence agar as a highly efficient homogenous catalyst in a mixture of (water/ethanol, 2:1). Based on the experiment data, the overall order of reaction for the formation of tetrahydrobenzo[b]pyran followed second-order kinetics and under pseudo-order conditions the partial orders with respect to 1, 2 and 3 were one, one and zero, respectively. From the temperature, concentration
doi:10.13005/bbra/2090
fatcat:6rrkh3jedrbl5dj5pgdjp2joee