Ru–Ag and Ru–Au dicarbene complexes from an abnormal carbene ruthenium system

Mario J. Bitzer, Alexander Pöthig, Christian Jandl, Fritz E. Kühn, Walter Baratta
2015 Dalton Transactions  
The first complexes containing an anionic dicarbene connected to two different d-block elements are reported. The synthetic pathway entails metalation and transmetalation reactions, starting from a cationic abnormal Ru-NHC complex.
doi:10.1039/c5dt01914a pmid:26053614 fatcat:mbem4bv2pzccxf6bymfvs5olxe