Monitoring of a fast-growing speleothem site from the Han-sur-Lesse cave, Belgium, indicates equilibrium deposition of the seasonal δ18O and δ13C signals in the calcite
M. Van Rampelbergh, S. Verheyden, M Allan, Y. Quinif, E. Keppens, P. Claeys
2014
Climate of the Past
<p><strong>Abstract.</strong> Speleothems provide paleoclimate information on multimillennial to decadal scales in the Holocene. However, seasonal or even monthly resolved records remain scarce. Such records require fast-growing stalagmites and a good understanding of the proxy system on very short timescales. The Proserpine stalagmite from the Han-sur-Less cave (Belgium) displays well-defined/clearly visible darker and lighter seasonal layers of 0.5 to 2 mm thickness per single layer, which
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... ows a measuring resolution at a monthly scale. Through a regular cave monitoring, we acquired a good understanding of how δ<sup>18</sup>O and δ<sup>13</sup>C signals in modern calcite reflect climate variations on the seasonal scale. From December to June, outside temperatures are cold, inducing low cave air and water temperature, and bio-productivity in the soil is limited, leading to lower <i>p</i>CO<sub>2</sub> and higher δ<sup>13</sup>C values of the CO<sub>2</sub> in the cave air. From June to December, the measured factors display an opposite behavior. <br><br> The absence of epikarst water recharge between May and October increases prior calcite precipitation (PCP) in the vadose zone, causing drip water to display increasing pH and δ<sup>13</sup>C values over the summer months. Water recharge of the epikarst in winter diminishes the effect of PCP and as a result the pH and δ<sup>13</sup>C of the drip water gradually decrease. The δ<sup>18</sup>O and δ<sup>13</sup>C signals of fresh calcite precipitated on glass slabs also vary seasonally and are both reflecting equilibrium conditions. Lowest δ<sup>18</sup>O values occur during the summer, when the δ<sup>13</sup>C values are high. The δ<sup>18</sup>O values of the calcite display seasonal variations due to changes in the cave air and water temperature. The δ<sup>13</sup>C values reflect the seasonal variation of the δ<sup>13</sup>C<sub>DIC</sub> of the drip water, which is affected by the intensity of PCP. This same anticorrelation of the &delta;<sup>18</sup>O versus the δ<sup>13</sup>C signals is seen in the monthly resolved speleothem record that covers the period between 1976 and 1985 AD. Dark layers display lower δ<sup>18</sup>O and higher δ<sup>13</sup>C values. The cave system varies seasonally in response to the activity of the vegetation cover and outside air temperature between a "summer mode" lasting from June to December and a "winter mode" from December to June. The low δ<sup>18</sup>O and high δ<sup>13</sup>C values of the darker speleothem layers indicate that they are formed during summer, while light layers are formed during winter. The darker the color of a layer, the more compact its calcite structure is, and the more negative its δ<sup>18</sup>O signal and the more positive its δ<sup>13</sup>C signal are. Darker layers deposited from summer drip water affected by PCP are suggested to contain lower Ca<sup>2+</sup> concentration. If indeed the calcite saturation represents the main factor driving the Proserpine growth rate, the dark layers should grow slower than the white layers.</p>
doi:10.5194/cp-10-1871-2014
fatcat:wlfstrjhlbfzrmd4fxefqkctjy