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Reaction of lutidine-bridged dibenzimidazolium dibromides 1 - 4 with palladium acetate gives pincer-type palladium complexes of the type [Pd(L)Br]Br Br-Br. Crystals suitable for an X-ray diffraction study have been obtained by slow evaporation of the solvent from dichloromethane/methanol solutions of Br and Br. The crystal structure of + reveals a pincer topology of the cationic complex with a distorted square-planar coordination geometry at the metal center. From a solution ofdoi:10.1515/znb-2007-0308 fatcat:xmakuh7h3rfuxcbmytsdsdwe5a