A systematic and detailed investigation of the structure of As x Te 100−x glasses ͑20ഛ x ഛ 60͒ has been undertaken using a combination of structure-probing techniques including high energy x-ray diffraction, neutron diffraction, and x-ray absorption fine structure measurements at the As and Te K edges. The experimental datasets were modeled simultaneously with the reverse Monte Carlo simulation technique. The results revealed that homonuclear bonding for both As and Te atoms is important over

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... e whole glass concentration region studied. At the stoichiometric composition ͑As 40 Te 60 ͒ the average As-As and Te-Te coordination numbers are as high as 1.7Ϯ 0.2 and 1.3Ϯ 0.1, respectively. The number of As-As and Te-Te bonds, as well as the average number of bonds/atom, evolves monotonically with composition. Arsenic atoms are threefold coordinated for all compositions investigated. It has also been shown that, in contrast to the results of previous studies, Te is predominantly twofold coordinated for x ഛ 50. Our results suggest that ͑i͒ chemical ordering does not play a decisive role in the formation of short-range order and ͑ii͒ similar to some other amorphous tellurides ͑e.g., Ge 2 Sb 2 Te 5 , GeSb 2 Te 4 , and As 25 Si 40 Te 35 ͒ binary As x Te 100−x ͑x ഛ 50͒ alloys obey the "8 − N" rule. A detailed comparison has been advanced between the structural details obtained from the present study and several physicochemical properties of As-Te. The comparison revealed striking similarities between the concentration dependence of structural and physicochemical properties.