Coordination chemistry in the solid state: synthesis and interconversion of pyrazolium salts, pyrazole complexes, and pyrazolate MOFs

Christopher J. Adams, Mukhtar A. Kurawa, A. Guy Orpen
2010 Dalton Transactions  
5 10 15 20 25 30 35 40 2theta/deg Counts XRPD for [CoCl 2 (Hpz) 2 ] 2 Blue = calculated from the crystal structure; green = mechanochemical; purple = 2[H 2 pz]Cl + Co(OH) 2 ; brown = 2[H 2 pz]Cl + CoCO 3 ; pink = 1 + 2KOH; turquoise = 1 + K 2 CO 3 . Electronic Supplementary Information for Dalton Transactions This journal is
doi:10.1039/c0dt00195c pmid:20556305 fatcat:67wm2oxdubbvjhzsm5w3g3tu4i