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Generating Cluster Formulas Using The Primary Clusters And The K(n) Parameters
2018
International Journal of Chemistry
The formulas of transition metal clusters can be regarded as multiples of their respective PRIMARY CLUSTERS and K(n) parameters. A primary cluster of a transition metal skeletal element can be defined as that cluster of a mono-skeletal element which obeys the 18 electron rule. Such clusters, among others include, Cr(CO)6, Fe(CO)5, Ni(CO)4, and Zn(CO)3 and the respective K values of the skeletal elements are 6, 5, 4 and 3. The selected K(n) series are given and the derived hypothetical golden
doi:10.5539/ijc.v10n2p85
fatcat:kyclnnnhknhtpmabwcovypwfrm