Do (pentaarylcyclopentadienyl)molybdenum(vi) dioxo species catalyse alkene epoxidations? Insights from kinetics data

Michael Pratt, Jason B. Harper, Stephen B. Colbran
2007 Dalton Transactions  
Supplementary Information Materials. Cyclooctene and tert-butylhydroperoxide (TBHP, 5.5 M in decane) were purchased from Aldrich and were stored over freshly-activated 4 Å molecular sieves. Cp ‡ MoO 2 Br was prepared by direct oxidation of Cp ‡ Mo(CO) 3 Br with dioxygen as previously reported. S1
doi:10.1039/b705571d pmid:17592590 fatcat:cjgxbnc6szavni74ukiphjzcwy