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Highly Selective Acyclic Stereocontrol Based on 1, 2-Rearrangement
1988
Journal of Synthetic Organic Chemistry, Japan
Highly Selective Acyclic Stereocontrol Based on 1,2-Rearrangement. Keisuke Suzum* Contrary to the firm and long-standing credence on the involvement of racemization , the "cationic" 1,2-rearrangement reactions may proceed stereospecifically under suitable reaction conditions to allow the complete 1, 2-chirality transfer. This fact provides a solid basis for the development of a novel and useful synthetic reactions to achieve the highly selective acyclic steoeocontrol. This paper deals with a
doi:10.5059/yukigoseikyokaishi.46.367
fatcat:jmusyrjkqfgepoywg5pdfk6xwu