A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2021; you can also visit the original URL.
The file type is
We report a methodology based on applying oscillating potentials to various electrocatalytically active metal surfaces during the formic acid oxidation reaction. Moderate frequency oscillations (0.1 to 10 Hz) allow us to control the coverage of intermediates on the surface, thus enable quantifying the transient effects (on the time scale of up to 10−4 s) of coverage on the reaction rate. We determined different coverage-dependences of turnover frequencies for Pt metal plate and variousdoi:10.26434/chemrxiv.13077485.v1 fatcat:mm2c4vzksnfw3ga2zxryslqqba