Internet Archive Scholar

Infrared studies and spectral properties of photochromic high silica glasses

Marina A. Girsova, Galina F. Golovina, Irina A. Drozdova, Irina G. Polyakova, Tatiana V. Antropova
2014

Preserved Fulltext

fulltext thumbnail
Web Archive Capture PDF (502.5 kB)
https://web.archive.org/web/20200207164331/http://opticaapplicata.pwr.edu.pl/files/pdf/2014/no2/optappl_4402p337.pdf

A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2020; you can also visit the original URL. The file type is application/pdf.

The structure of photochromic high silica glasses (PHSGs) was studied by UV-VIS-NIR and IR spectroscopy, transmission electron microscopy (TEM) and X-ray diffraction (XRD) techniques. PHSG plates were obtained by impregnation of silica porous glasses at first with AgNO 3 aqueous solution (in or without the presence of the sensitizers, such as Cu(NO 3 ) 2 or Ce(NO 3 ) 3 ), next in the mixed halide salt (NH 4 Cl, KBr, KI) solution. Then a part of the samples was sintered at temperatures from 850
more » ... o 900°C up to closing of the pores. The results of TEM study have shown that the PHSG plates have two-phase structure with inclusions of the size of 10-100 nm. According to XRD data, the PHSGs contain the AgBr phase. IR spectra confirmed the presence of AgI, AgCl, CeO 2 , CuCl 2 , CuCl phases in PHSGs.
doi:10.5277/oa140214 fatcat:y5kk27tmgnf2bl2rgx7rn4jq4e
Citation

Marina A. Girsova, Galina F. Golovina, Irina A. Drozdova, Irina G. Polyakova, Tatiana V. Antropova. "Infrared studies and spectral properties of photochromic high silica glasses." (2014)