UV PHOTODESORPTION OF METHANOL IN PURE AND CO-RICH ICES: DESORPTION RATES OF THE INTACT MOLECULE AND OF THE PHOTOFRAGMENTS

Mathieu Bertin, Claire Romanzin, Mikhail Doronin, Laurent Philippe, Pascal Jeseck, Niels Ligterink, Harold Linnartz, Xavier Michaut, Jean-Hugues Fillion
2016 Astrophysical Journal Letters  
Wavelength dependent photodesorption rates have been determined using synchrotron radiation, for condensed pure and mixed methanol ice in the 7 -- 14 eV range. The VUV photodesorption of intact methanol molecules from pure methanol ices is found to be of the order of 10^-5 molecules/photon, that is two orders of magnitude below what is generally used in astrochemical models. This rate gets even lower (< 10^-6 molecules/photon) when the methanol is mixed with CO molecules in the ices. This is
more » ... sistent with a picture in which photodissociation and recombination processes are at the origin of intact methanol desorption from pure CH_3OH ices. Such low rates are explained by the fact that the overall photodesorption process is dominated by the desorption of the photofragments CO, CH_3, OH, H_2CO and CH_3O/CH_2OH, whose photodesorption rates are given in this study. Our results suggest that the role of the photodesorption as a mechanism to explain the observed gas phase abundances of methanol in cold media is probably overestimated. Nevertheless, the photodesorption of radicals from methanol-rich ices may stand at the origin of the gas phase presence of radicals such as CH_3O, therefore opening new gas phase chemical routes for the formation of complex molecules.
doi:10.3847/2041-8205/817/2/l12 fatcat:222kdfd3kvb4poobsymne2ygpe